Milke, E.; Köppe, R.; Binnewies, Michael
(Cambridge : Royal Society of Chemistry, 2011)
By reaction of solid As4S4 with gaseous Cl2 at a temperature of 410 K gaseous AsSCl and AsS2Cl are formed. Unexpectedly in AsS2Cl the arsenic is not of formal oxidation state +V but +III: the molecular structure of AsS2Cl ...